1044869-08-0Relevant articles and documents
A bidirectional tunnel-like structure with a rigid, thick, and chiral aromatic macrocycle prepared by self-complementary 6,6′-substituted binaphthyl monomer
Kumeda, Kazuhiro,Ono, Munetosi,Kawai, Atsushi,Oike, Hideaki,Noguchi, Keiichi,Yonezawa, Noriyuki
, p. 660 - 661 (2008)
A rigid, thick, and optically active aromatic macrocycle having 6,6′-binaphthylylene moieties was successfully obtained in a moderate yield by synthesis and SNAr of 6-(4-fluorobenzoyl)-6′-hydroxy-2,2′- dimethoxy-1,1′-binaphthyl. The X-ray crystal structural analysis of the obtained macrocycle reveals rigid concavo-concave shape of the molecule and the bidirectional tunnel-like structure assembly consisting of two types of channels along a axis and c axis originated by intra- and intermolecular cavities, respectively. Copyright