104495-16-1

Upstream product

• 108-94-1 cyclohexanone 
• 104495-11-6 6-benzenesulfonyl-3-O-benzyl-6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose 
• 23313-03-3 (R)-2-[(3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-2-hydroxyethyl 4-methylbenzenesulfonate 
• 22529-61-9 (1R)-1-((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro(2,3-d)(1,3)dioxol-5-yl)ethane-1,2-diol 
• 118149-32-9 ((phenylsulfonyl)methyl)magnesium bromide 
• 118149-34-1 (S)-1-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-2-phenylsulfanyl-ethanol 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 

Relevant academic research and scientific papers

SYNTHESIS OF HIGHER-CARBON SUGARS: PREPARATION AND REACTION OF β-HYDROXYSULFONYL SUGARS

β-Hydroxysulfonyl sugars 4 and 5 were prepared by addition of phenylsulfonylmethide to a dialdose 3 and by oxidation of a sulfide sugar 8 with H2O2-H2SeO3.The dianion of 4 was stable at low temperature and reacted with carbon electrophiles to provide vari