104501-76-0Relevant academic research and scientific papers
Thermal Rearrangements of N-Aryl-1-alkynesulphenamides into Indoline-2-thiones
Baudin, J.-B.,Bekhazi, M.,Julia, S. A.,Ruel, O.,Jong, R. L. P. de,Brandsma, L.
, p. 956 - 958 (2007/10/02)
Reaction of bromomagnesium benzenamides with 1-alkynyl thiocyanates affords the title sulphenamides.On heating in benzene, these sulphenamides undergo -sigmatropic rearrangements followed by cyclisation of the intermediate thioketenes yielding indoli
