104501-94-2Relevant articles and documents
SYNTHESES OF β,β-DIFLUOROCARBOXYLIC ACID DERIVATIVES THROUGH THE CLAISEN REARRANGEMENT OF 1,1-DIFLUORO-1-ALKEN-3-OLS
Taguchi, Takeo,Morikawa, Tsutomu,Kitagawa, Osamu,Mishima, Takashi,Kobayashi, Yoshiro
, p. 5137 - 5140 (2007/10/02)
3,3-Difluoro-4-alkenoic esters (3) were obtained through the Claisen rearrangement of 1,1-difluoro-1-alken-3-ols (1) with ortho ester.Keywords-Claisen rearrangement; 1,1-difluoroethene; dibromodifluoromethane; trimethyl orthoacetate