104504-79-2

Upstream product

• 19159-39-8 phenylglyoxal dimethylacetal 
• 104504-76-9 methyl 2-carbomethoxy-3-hydroxy-4-phenyl-4-oxo-butanoate dimethyl ketal 
• 104504-77-0 methyl 2-carbomethoxy-4-phenyl-4-oxo-butenoate dimethyl ketal 
• 2648-61-5 2,2-dichloroacetophenone 
• 104504-78-1 5-benzoyldimethylketal-1-benzyl-4,4-dicarbomethoxy-1,2,3-triazoline 

Relevant academic research and scientific papers

Thermolysis of 5-acyltriazolines. Formation of enamides. Reaction mechanism

The thermolysis of 5-acyltriazolines 1, 2, 3 (X=COR', Y=CO2Me) was studied.Instead of the expected aziridines, enamides 5 to 8 were obtained by an unusual acyl migration.It has been shown that the reaction is intramolecular and proceeds via a 1,2 followed