1045346-01-7Relevant academic research and scientific papers
Regio- and stereoselective behavior of l-arabinal-derived vinyl epoxide in nucleophilic addition reactions. Comparison with conformationally restricted d-galactal-derived analogs
Di Bussolo, Valeria,Frau, Ileana,Favero, Lucilla,Uccello-Barretta, Gloria,Balzano, Federica,Crotti, Paolo
, p. 6276 - 6284 (2015)
Abstract The regio- and stereoselectivity of the addition reactions of O-, C-, N-, and S-nucleophiles to l-arabinal-derived vinyl epoxide 2, the simplest non-conformationally restricted glycal-derived vinyl epoxide, has been examined and compared with the
[2,3]-Sigmatropic rearrangements of 3-sulfinyl dihydropyrans: application to the syntheses of the cores of ent-dysiherbaine and deoxymalayamicin A
De La Pradilla, Roberto Fernandez,Lwoff, Nadia,Del Aguila, Miguel Angel,Tortosa, Mariola,Viso, Alma
supporting information; experimental part, p. 8929 - 8941 (2009/04/05)
(Chemical Equation Presented) The [2,3]-sigmatropic rearrangement of a variety of configurationally stable diastereomeric allylic sulfinyl dihydropyrans, produced by base-promoted cyclization of sulfinyl dienols, has been studied. In some cases, the effic
