1045346-26-6Relevant academic research and scientific papers
[2,3]-Sigmatropic rearrangements of 3-sulfinyl dihydropyrans: application to the syntheses of the cores of ent-dysiherbaine and deoxymalayamicin A
De La Pradilla, Roberto Fernandez,Lwoff, Nadia,Del Aguila, Miguel Angel,Tortosa, Mariola,Viso, Alma
scheme or table, p. 8929 - 8941 (2009/04/05)
(Chemical Equation Presented) The [2,3]-sigmatropic rearrangement of a variety of configurationally stable diastereomeric allylic sulfinyl dihydropyrans, produced by base-promoted cyclization of sulfinyl dienols, has been studied. In some cases, the effic
Sulfur-directed enantioselective synthesis of functionalized dihydropyrans
De La Pradilla, Roberto Fernandez,Tortosa, Mariola,Lwoff, Nadia,Del Aguila, Miguel A.,Viso, Alma
, p. 6716 - 6727 (2008/12/22)
(Chemical Equation Presented) The highly selective base-promoted cyclization of enantiopure sulfinyl dienols affords allylic sulfinyl dihydropyrans. The scope of this methodology, including the preparation of seven-membered rings, has been studied in dept
