104639-06-7Relevant academic research and scientific papers
Stereoselective Total Synthesis of (+/-)-3-Oxosilphinene through Intermolecular Diels-Alder Reaction
Ihara, Masataka,Kawaguchi, Akihiro,Ueda, Hitoshi,Chihiro, Masatoshi,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1331 - 1338 (2007/10/02)
The angular tricyclopentanoid sesquiterpene (+/-)-3-oxosilphinene (1) was stereoselectively synthesized through intramolecular Diels-Alder reaction as the key step.On heating, the (E,E)-sulphenyltriene (16), derived from 3-bromo-2-methylcyclopent-2-enone
Highly Stereocontrolled Synthesis of (+/-)-3-Oxosilphinene via Intramolecular Diels-Alder Reaction
Ihara, Masataka,Kawaguchi, Akihiro,Chihiro, Masotoshi,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 671 - 672 (2007/10/02)
The angularly fused triquinane, (+/-)-3-oxosilphinene (4), was stereoselectively synthesised via an intramolecular Diels-Alder reaction as the key step.
