104641-37-4

Upstream product

• 87902-35-0 (3aR,4R,5S,6S,7R,7aR)-6-Amino-5,7-dihydroxy-4-methoxy-3-methyl-hexahydro-benzooxazol-2-one 
• 87902-27-0 (1R,2R)-2-Methylamino-cyclohex-3-enol 
• 87902-28-1 ((1R,6R)-6-Methoxy-cyclohex-2-enyl)-methyl-carbamic acid methyl ester 
• 87902-29-2 (3aS,4R,7S,7aS)-7-Bromo-4-methoxy-3-methyl-hexahydro-benzooxazol-2-one 
• 87782-14-7 (3aS,4R,7S,7aS)-7-Hydroxy-4-methoxy-3-methyl-3a,4,7,7a-tetrahydro-3H-benzooxazol-2-one 
• 87902-33-8 (1aS,2S,2aR,5aR,6R,6aR)-2-Hydroxy-6-methoxy-5-methyl-hexahydro-1,3-dioxa-5-aza-cyclopropa[f]inden-4-one 
• 6705-51-7 1,3-cyclohexadiene monoepoxide 
• 87902-30-5 DL-(1α,2α,3β,4β,5α)-1,2-anhydro-3-O,4-N-carbonyl-5-O-methyl-4-(methylamino)-1,2,3,5-cyclohexanetetrol 
• 1165952-91-9 cyclohexa-1,3-diene 
• 104641-36-3 (+)-(1S)-(1α,2α,3β,4α,5β,6β)-3-(Acetylamino)-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-1,2,4,5-cyclohexanetetrol 2,4-Diacetate 
• 104600-57-9 DL-(1α,2β,3β,4β,5β,6α)-2,3-Anhydro-4-O-benzyl-1-O,6-N-carbonyl-6-(methylamino)-1,2,3,4,5-cyclohexanepentol 
• 104600-58-0 DL-(1α,2β,3β,4β,5β,6α)-2,3-Anhydro-4-O-benzyl-1-O,6-N-carbonyl-5-O-methyl-6-(methylamino)-1,2,3,4,5-cyclohexanepentol 
• 104600-54-6 DL-(1α,2β,3β,4β,5β,6α)-2,3-Anhydro-4-O-benzyl-1-O,6-N-carbonyl-6-(methylamino)-1,2,3,4,5-cyclohexanepentol 5-Acetate 
• 104712-72-3 (+)-(1S)-(1α,2α,3β,4α,5β,6β)-2-O-Benzyl-5-O,6-N-carbonyl-1-O-methyl-6-(methylamino)-3-<(R)-(1-phenylethyl)amino>-1,2,4,5-cyclohexanetetrol 

Relevant academic research and scientific papers

Total Synthesis of (+/-)-Fortamine and (+/-)-2-Deoxyfortamine

The efficient conversion of 1,3-cyclohexadiene (7) to the aminocyclitols (+/-)-fortamine (4, 13 steps, 30percent overall yield) and (+/-)-2-deoxyfortamine (5, 10 steps, 54percent overall yield) features four regiospecific epoxide-opening reactions.