104659-49-6Relevant academic research and scientific papers
THE CHEMISTRY OF 1,3,4-THIADIAZOLINE-2-SPIRO-2'-FENCHANE.
Huisgen, Rolf,Mloston, Grzegorz,Proebstl, Albert
, p. 4431 - 4434 (2007/10/02)
Diazomethane adds to one of the two faces of the sterically hindered thiofenchone furnishing the title compound wich extrudes N2 at 46 deg C whith t1/2=22 min; the thiofenchone S-methylide is intercepted by dipolarophiles and acts as a base in reactions with methanol, thiophenol and acetic acid, in the latter case accompanied by skeletal rearrangement.
