10468-25-4Relevant academic research and scientific papers
Reactions of silylcarbamates with ketones
Kardon,Mortl,Knausz
, p. 8937 - 8939 (2000)
The reaction of N,N-dialkyl-O-trimethylsilyl carbamates with different carbonyl compounds gives enamines under mild conditions in good yields. (C) 2000 Elsevier Science Ltd.
THE ?-BARRIER TO ROTATION IN STERICALLY UNHINDERED ENAMINES: CONFORMATIONAL STUDIES BY DYNAMIC NMR, XXXVIII
Lunazzi, Lodovico,Casarini, Daniele,Anderson, J.Edgar
, p. 217 - 221 (2007/10/02)
The ?-barriers to rotation about the enamine (N-Csp2) bond in four pyrrolidinocyclo-n-alkenes (n = 5, 6, 7, 8) have been determined, and are discussed in terms of the steric interactions between the pyrrolidine and cycloalkene rings in the ground state.Distinct barriers were determined for two different conformations of the cyclooctene ring.Barriers were determined in two acyclic N,N-(dialkylamino)cycloalkenes for reference comparison.
