10468-76-5Relevant academic research and scientific papers
Kinetics and mechanism of oxidation of 4-oxoacids by hexacyanoferrate(III) catalysed by Os(VIII)
Gnana Rani, D. Freeda,Pushparaj, F. J. Maria,Alphonse,Rangappa
, p. 2153 - 2159 (2007/10/03)
Kinetics of Os(VIII) catalysed oxidation of substituted and unsubstituted 4-oxoacids by alkaline hexacyanoferrate(III) in sodium carbonate-bicarbonate buffer have been studied. The reaction is zero order in oxidant, first order with respect to Os(VIII), first order at higher concentrations and zero order at lower concentrations with respect to both substrate and alkali. The activation parameters have been computed.
