1046809-03-3Relevant academic research and scientific papers
β-Halovinylsilanes in oligoyne synthesis: a fluoride-catalysed unmasking of alkynes from β-fluorovinylsilanes
Weller, Michael D.,Kariuki, Benson M.,Cox, Liam R.
, p. 4596 - 4600 (2008/09/21)
A stereoselective halodestannylation of (E)-β-stannylvinylsilane 6 has been used to access a range of (E)-β-halovinylsilanes. Most notably, the β-fluorovinylsilane 14 was accessed in high yield using the Selectfluor reagent, and subsequently converted into a masked hexayne 22. Release of the hexayne 25 was achieved by exposing 22 to sub-stoichiometric quantities of fluoride.
