104702-32-1

Basic information

• Product Name: hexyl 2-(methylammonio)ethyl phosphate
• Synonyms: Phosphoric acid, monohexyl mono(2-(methylamino)ethyl) ester; Phosphoric acid, monohexyl mono[2-(methylamino)ethyl] ester
• CAS NO: 104702-32-1
• Molecular Formula: C₉H₂₂NO₄P
• Molecular Weight: 239.249
• Mol File: 104702-32-1.mol

Chemical Properties

• Boiling Point: 328.8°C at 760 mmHg
• Flash Point: 152.7°C
• Density: 1.086g/cm³
• Vapor Pressure: 3.65E-05mmHg at 25°C
• Refractive Index: 1.45
• CAS DataBase Reference: hexyl 2-(methylammonio)ethyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: hexyl 2-(methylammonio)ethyl phosphate(104702-32-1)
• EPA Substance Registry System: hexyl 2-(methylammonio)ethyl phosphate(104702-32-1)

Safety Data

• Hazardous Substances Data: 104702-32-1(Hazardous Substances Data)

Upstream product

• 111-27-3 hexan-1-ol 
• 104702-23-0 2-Hexyloxy-3-methyl-1,3,2-oxazaphosphacyclopentane 
• 104702-27-4 2-Hexyloxy-3-methyl-1,3,2-oxazaphosphacyclopentane 2-oxide 

Relevant articles and documents

A New and Rapid Synthesis of Phospholipids

Reaction of 2-chloro-3-methyl-1,3,2-oxazaphosphacyclopentane with long chain alcohols gives cyclic alkyl phosphoramidities, which yield alkyl phosphoryl N-methylethanolamines on dinitrogen tetroxide oxidation and acid hydrolysis.

Synthesis of Phospholipids by Phosphoramidite Methodology

Novel phospholipids have been prepared by a rapid three-step procedure.The oxazaphosphacyclopentane (1) reacts with alcohols to yield cyclic phosphoramidites in high yield.These are oxidised to the corresponding phosphates with N2O4.The phosphates undergo P-N cleavage simply by treatment with water at ambient temperature, to yield phospholipids.Full spectroscopic and analytical data are presented and discussed.