104731-69-3

Upstream product

• 10226-78-5 methyl DL-(1,3,4/2,5)-2,3,4,5-tetra-O-acetyl-2,3,4,5-tetrahydroxycyclohexane-1-carboxylate 
• 104731-67-1 DL-(1,3/2)-2,3-Diacetoxy-4-cyclohexene-1-carboxylic acid 
• 10226-78-5 methyl DL-(1,3/2,4,5)-2,3,4,5-tetra-acetoxycyclohexane-1-carboxylate 
• 69982-67-8 DL-2-exo-bromo-4,8-dioxatricyclo<4.2.1.0^3,7>nonan-5-one 
• 104765-18-6 methyl DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylate 
• 104748-84-7 DL-(1,3,5/2,4)-2,3-diacetoxy-4,5-dibromocyclohexane-1-carboxylic acid 
• 104731-68-2 methyl DL-(1,3/2)-2,3-di-O-acetyl-2,3-dihydroxy-4-cyclohexene-1-carboxylate 
• 104731-71-7 methyl DL-(1,3/2,4,5)-2,3-diacetoxy-4,5-epoxycyclohexane-1-carboxylate 
• 104731-71-7 methyl DL-(1,3,4,5/2)-2,3-diacetoxy-4,5-epoxycyclohexane-1-carboxylate 

Downstream Products

• 15271-51-9 (+/-)-shikimic acid 
• 4372-89-8 (+/-)-methyl shikimate 
• 16613-45-9 (+/-)-methyl triacetylshikimate 
• 113409-79-3 methyl DL-(1,3,4/2,5)-2,3,4,5-tetrahydroxy-2-O-p-tolylsulfonylcyclohexane-1-carboxylate 
• 113409-80-6 methyl DL-(1,3,4/2,5)-2,3,4,5-tetrahydroxy-5-O-p-tolylsulfonylcyclohexane-1-carboxylate 
• 113445-09-3 (3aR,4R,5S,7S,7aR)-7-Hydroxy-2,2-dimethyl-4-(toluene-4-sulfonyloxy)-hexahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 113445-10-6 (3aS,4R,5S,7S,7aS)-4-Hydroxy-2,2-dimethyl-7-(toluene-4-sulfonyloxy)-hexahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 113409-81-7 methyl DL-(1,3,4/2,5)-2,3,4,5-tetrahydroxy-2,5-di-O-p-tolylsulfonylcyclohexane-1-carboxylate 
• 113409-78-2 (3aS,4S,5R,7R,7aR)-2,2-Dimethyl-4,7-bis-(toluene-4-sulfonyloxy)-hexahydro-benzo[1,3]dioxole-5-carboxylic acid methyl ester 
• 113409-82-8 methyl DL-(3,4/5)-3,4,5-trihydroxy-5-O-p-tolylsulfonyl-cyclohexene-1-carboxylate 

Relevant academic research and scientific papers

SYNTHESIS OF METHYL DL-(1,3/2,4,5)- AND DL-(1,3,4/2,5)-2,3,4,5-TETRAHYDROXYCYCLOHEXANE-1-CARBOXYLATES

Two new diastereoisomers of the pseudo-hexuronate methyl 2,3,4,5-tetrahydroxycyclohexane-1-carboxylate, having (1,3/2,4,5)- (8) and (1,3,4/2,5)-configurations (16), have been synthesized from the readily available bromo-lactone (1) of the endo-adduct of f