104755-16-0

Upstream product

• 42572-42-9 phenylselenium trichloride 
• 93-08-3 methyl 2-naphthyl ketone 

Downstream Products

• 125731-82-0 C₁₈H₁₃Cl₃OSe 
• 125731-96-6 2,2-Dichloro-1-naphthalen-2-yl-2-phenylselanyl-ethanone 
• 125731-71-7 2-Chloro-1-naphthalen-2-yl-2-phenylselanyl-ethanone 
• 104755-33-1 1-(naphthalen-2-yl)-2-(phenylselanyl)ethan-1-one 

Relevant academic research and scientific papers

A radical cyclization route to cyclic imines

A novel route to cyclic imines based on 5-exo radical cyclization is explored. The radical precursors are imines prepared from allylamine and readily available α-phenylselenenyl ketones.

PUMMERER-LIKE REACTION OF SELENIUM(IV)-DICHLORIDES. SYNTHESIS OF α-CHLORO-α-PHENYLSELENENYLKETONES AND α,α-DICHLORO-α-PHENYLSELENENYLKETONES

Selenium(IV)-dichlorides 1, readily available by treatment of methyl ketones with phenylselenium trichloride or selenium tetrachloride, were treated in methylene chloride with pyridine to give α-chloroselenides 2 in a Pummerer-like reaction.Sulfuryl chlor

PHENYL SELENIUM TRICHLORIDE IN SYNTHESIS. REACTION WITH KETONES. A NEW VARIATION OF THE SELENOXIDE ELIMINATION REACTION

Phenyl selenium trichloride was used for the introduction of a PhSeCl2-group into the α-position of ketones.These products were converted to enones (hydrolysis/selenoxide elimination) or α-phenylselenoketones (thiourea-reduction).