104755-16-0Relevant articles and documents
A radical cyclization route to cyclic imines
Srivastava, Puneet,Engman, Lars
scheme or table, p. 1149 - 1151 (2010/04/05)
A novel route to cyclic imines based on 5-exo radical cyclization is explored. The radical precursors are imines prepared from allylamine and readily available α-phenylselenenyl ketones.
PUMMERER-LIKE REACTION OF SELENIUM(IV)-DICHLORIDES. SYNTHESIS OF α-CHLORO-α-PHENYLSELENENYLKETONES AND α,α-DICHLORO-α-PHENYLSELENENYLKETONES
Engman, Lars,Persson, Joachim,Tilstam, Ulf
, p. 2665 - 2668 (2007/10/02)
Selenium(IV)-dichlorides 1, readily available by treatment of methyl ketones with phenylselenium trichloride or selenium tetrachloride, were treated in methylene chloride with pyridine to give α-chloroselenides 2 in a Pummerer-like reaction.Sulfuryl chlor
PHENYL SELENIUM TRICHLORIDE IN SYNTHESIS. REACTION WITH KETONES. A NEW VARIATION OF THE SELENOXIDE ELIMINATION REACTION
Engman, Lars
, p. 6385 - 6388 (2007/10/02)
Phenyl selenium trichloride was used for the introduction of a PhSeCl2-group into the α-position of ketones.These products were converted to enones (hydrolysis/selenoxide elimination) or α-phenylselenoketones (thiourea-reduction).
