104764-64-9

Basic information

• Product Name: Acetic acid (2R,3S)-4-methylene-3-phenyl-tetrahydro-furan-2-yl ester
• Synonyms: Acetic acid (2R,3S)-4-methylene-3-phenyl-tetrahydro-furan-2-yl ester
• CAS NO: 104764-64-9
• Molecular Weight: 218.252
• Mol File: 104764-64-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (2R,3S)-4-methylene-3-phenyl-tetrahydro-furan-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2R,3S)-4-methylene-3-phenyl-tetrahydro-furan-2-yl ester(104764-64-9)
• EPA Substance Registry System: Acetic acid (2R,3S)-4-methylene-3-phenyl-tetrahydro-furan-2-yl ester(104764-64-9)

Safety Data

• Hazardous Substances Data: 104764-64-9(Hazardous Substances Data)

Upstream product

• 3375-31-3 palladium diacetate 
• 79164-20-8 ((E)-2-Allyloxy-vinyl)-benzene 

Downstream Products

• 104746-69-2 3-Methyl-4-phenyl-furan 
• 104746-99-8 4-Methyl-3-phenyl-2,5-dihydro-furan-2-ol 

Relevant articles and documents

INTERCEPTION OF TETRAHEDRAL INTERMEDIATES IN Pd(II)-MEDIATED CYCLOALKENYLATIONS OF OLEFINIC ENOL ETHERS

The tetrahedral intermediate 3 has been intercepted during Pd(II)-cycloalkenylation of olefinic enolsilane 1 (R=SiMe2t-Bu).In a related manner, the allyl and crotyl enol ethers 5-8 give with Pd(OAc)2 acetoxy tetrahydrofurans (9, 12, 14, 16), convertible to butyrolactones or furans; competing Pd(II)-mediated Claisen rearrangement was not observed.The intramolecular Pd(II)-cycloalkenylation of the ketene acetal 17 leads to δ-lactones 18 and 19.