104805-06-3Relevant academic research and scientific papers
CATALYTIC USE OF TIN(II) REAGENTS IN ORGANIC SYNTHESIS
Iwasawa, Nobuharu,Yura, Takeshi,Mukaiyama, Teruaki
, p. 1197 - 1208 (2007/10/02)
New carbon-carbon bond forming reactions using a catalytic amount of tin(II) reagents have been developed.Namely, an aldol type reaction of tin(II) enolate is achieved starting from α,β-unsaturated ketone, aldehyde and ethylthiotrimethylsilane in the presence of a catalytic amount of tin(II) triflate sulfide.Furthermore, the catalytic asymmetric Michael reaction of tin(II) enethiolate is realized just by using a catalytic amount of tin(II) triflate-chiral diamine complex.
