10481-12-6Relevant academic research and scientific papers
ALLYLPALLADIUM(II) COMPLEXES DERIVED FROM 1,2,6-HEPTATRIENE AND 1,2,8-NONATRIENE
Powell, John,Dowling, Norman I.
, p. 387 - 398 (1984)
The reaction of 1,2,6-heptatriene with PdCl2(PhCN)2 gives a mixture of di-μ-chlorodidi-palladium(II) and di-μ-chloro-di(η3-2-methylene-3-chlorocyclohexyl)dipalladium(II) which could not be separated by conventional techniques.The structures of these compounds are ascertained from a study of the 1H and 13C NMR spectra and chemical properties of the mixture.A mechanism is proposed to account for the formation of the cyclic η3-2-methylene-3-chlorocyclohexyl ligand.A corresponding reaction of 1,2,8-nonatriene with PdCl2(PhCN)2gives di-μ-chlorodidipalladium(II) as the sole product.
