104829-07-4Relevant academic research and scientific papers
Synthesis of 1,1-Bis(seleno)-2-alkenes
Dieden, R.,Hevesi, L.
, p. 616 - 619 (2007/10/02)
The success of the direct conversion of α,β-unsaturated carbonyl compounds into the corresponding diselenoacetals by means of selenol/zinc chloride or tris(seleno)borane greatly depends on the starting carbonyl derivative.Enals and cyclic enones are transformed most efficiently, whereas acyclic enones mainly produce 1,4-addition compounds.
REGIO- AND STEREOCHEMISTRY OF THE ZnCl2 MEDIATED CONVERSION OF 3-HYDROXYVINYL SELENIDES INTO 1,3-BIS(SELENO)-PROPENES
Renard, M.,Hevesi, L.
, p. 1885 - 1888 (2007/10/02)
The title process extends the scope of a recently reported reaction, gives general access to the largely unknown 1,3-bis(seleno)-propenes and reveals interesting aspects of allylic nucleophilic substitution.
