104830-17-3

Basic information

• Product Name: N-(2-cyanobenzylidene)-4-methoxyaniline
• Synonyms: N-(2-cyanobenzylidene)-4-methoxyaniline
• CAS NO: 104830-17-3
• Molecular Weight: 236.273
• Mol File: 104830-17-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(2-cyanobenzylidene)-4-methoxyaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-cyanobenzylidene)-4-methoxyaniline(104830-17-3)
• EPA Substance Registry System: N-(2-cyanobenzylidene)-4-methoxyaniline(104830-17-3)

Safety Data

• Hazardous Substances Data: 104830-17-3(Hazardous Substances Data)

Upstream product

• 7468-67-9 o-formylbenzonitrile 
• 104-94-9 4-methoxy-aniline 

Downstream Products

• 160956-25-2 isoindole-1,3-diylidenediamine 
• 104830-22-0 1--1,3-diiminoisoindoline 

Relevant articles and documents

Ir-Catalyzed C?H Amidation of Aldehydes with Stoichiometric/Catalytic Directing Group

Ir-catalyzed sp2C?H amidation of aldehydes with various anilines as stoichiometric or catalytic directing groups was accomplished. A wide range of substrates were selectively amidated in good to excellent yields with broad functional group tolerance. The iridacycle complexes were isolated, characterized, and proved as key intermediates. Kinetic studies and Hammett plots provided detailed understandings of this amidation. According to the mechanism, the electron-rich ArSO2N3was proved effective for intermolecular sp3C?H amidation.

SYNTHESIS OF 1,3-DIIMINOISOINDOLINES FROM 2-CYANOBENZALDEHYDE. REACTION OF N-(2-CYANOBENZYLIDENE)ANILINES WITH ELEMENTAL SULFUR IN LIQUID AMMONIA AND AMINES

Various 1,3-diiminoisoindolines were obtained by treating N-(2-cyanobenzylidene)anilines with elemental sulfur in liquid ammonia and amines.A novel route to isoindoline from 2-cyanobenzaldehyde was developed.