104832-35-1

Upstream product

• 17920-90-0 3,3,7-trimethyl-oct-6-enal 
• 5392-40-5 (E/Z)-3,7-dimethyl-2,6-octadienal 
• 106-26-3 cis-3,7-dimethyl-2,6-octadienal 
• 106-24-1 Geraniol 
• 141-27-5 3,7-dimethyl-2,6-octadienal 

Downstream Products

• 107259-70-1 (1S,2R)-trans-2-isopropyl-5,5-dimethylcyclohexanol 
• 107259-69-8 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2R)-2-isopropenyl-5,5-dimethyl-cyclohexyl ester 
• 107259-69-8 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1S,2R)-2-isopropenyl-5,5-dimethyl-cyclohexyl ester 

Relevant academic research and scientific papers

Identification of Reaction Sites on Metal-Organic Framework-Based Asymmetric Catalysts for Carbonyl-Ene Reactions

The characteristics of catalytic sites in metal-organic framework (MOF)-based catalysts could be approximately classified by their location, i.e., the inside of the pore and/or on the surface of the crystal. This classification of catalytic sites in a sin

The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations

The effect of host structure on the selectivity and mechanism of intramolecular Prins reactions is evaluated using K12Ga4L6 tetrahedral catalysts. The host structure was varied by modifying the structure of the chelating moieties and the size of the aromatic spacers. While variation in chelator substituents was generally observed to affect changes in rate but not selectivity, changing the host spacer afforded differences in efficiency and product diastereoselectivity. An extremely high number of turnovers (up to 840) was observed. Maximum rate accelerations were measured to be on the order of 105, which numbers among the largest magnitudes of transition state stabilization measured with a synthetic host-catalyst. Host/guest size effects were observed to play an important role in host-mediated enantioselectivity.

NOVEL LACTONE COMPOUND AND NOVEL ETHER COMPOUND

A lactone compound is represented by general formula (A), and an ether compound is represented by general formula (B). In formula (A), R is a hydrogen atom or R1. When R is a hydrogen atom, R′ is R1, the carbon bond (1) is a single bond or a double bond, and the carbon bond (2) is a single bond. When R is R1, R′ is a hydrogen atom or R1, both the carbon bonds (1) and (2) are a single bond, or one of them is a double bond and the other is a single bond. In formula (B), R″ is R1. R1 represents a specific alkyl group, a specific alkenyl group, a specific alkynyl group, or an aryl group. In formulas (A) and (B), n is 0 or 1.

METHYL MENTHOL DERIVATIVE AND COOLING AGENT COMPOSITION CONTAINING SAME

The purpose of the present invention is to provide a cooling agent composition containing a novel methyl menthol derivative having no undesirable feeling of stimulation, malodor, bitterness, or the like, it being possible to use the cooling agent composit

Pyrophosphoric acid ester compound, bisphosphate ester compound and catalyst

The invention pertains to a novel pyrophosphoric acid ester compound represented by formula (1) and a bisphosphoric acid ester compound represented by formula (2). In the formulas, R is an aryl group, organic silyl group, or halogen atom. These compounds can adequately activate carbonyl compounds, imine compounds, and the like due to having higher acidity than conventional phosphoric acid ester compounds. Usefulness as a metal ligand is also expected.

Cationic Chiral Fluorinated Oxazaborolidines. More Potent, Second-Generation Catalysts for Highly Enantioselective Cycloaddition Reactions

The coordination of chiral ligands to Lewis acid metal derivatives, a useful strategy for enantioselective, electrophilic catalysis, generally leads to a lower level of catalytic activity than that of the original uncomplexed compound. Activation by furth

MANUFACTURING METHOD OF OPTICAL ACTIVE ALCOHOL

PROBLEM TO BE SOLVED: To provide a method for providing optical active alcohol capable of being a perfume material or a cold sensation raw material with high optical purity and high selectivity by conducting an asymmetric carbonyl-en ring closure reaction

Chiral environment of catalytic sites in the chiral metal-organic frameworks

Chiral metal-organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place

BINOL-Al catalysed asymmetric cyclization and amplification: Preparation of optically active menthol analogs

We report a highly selective asymmetric ring-closing ene reaction catalysed by aluminum complexes with chiral BINOL. This reaction yields optically active 6-membered cyclized alcohols from unsaturated aldehydes, with good diastereo- and enantioselectiviti