104847-01-0Relevant academic research and scientific papers
Stereoselective Addition of R2CuLi to ortho-Substituted Methyl Cinnamates. Intramolecular Assistance and Solvent Effects
Christenson, Beritte,Hallnemo, Gerd,Ullenius, Christina
, p. 4739 - 4752 (2007/10/02)
High chemical yields are obtained on the addition of the ortho-substituted enoates 1, 2, 3, and 4 to Me2CuLi or Ph2CuLi in non-coordinating solvents, CH2Cl2 or toluene.The results underline the strong effect of solvent on reactions between organocuprates
INTRAMOLECULARLY ASSISTED ADDITION OF LiMe2Cu TO METHYL CINNAMATES
Hallnemo, Gerd,Ullenius, Christina
, p. 395 - 398 (2007/10/02)
Some ortho-substituted methyl cinnamates have been prepared and their reaction with lithium dimethylcuprate investigated.A methoxymethyl group in the ortho-position caused a ten-fold enhancement of the reaction rate relative to methyl cinnamate, while the
