104863-83-4

Basic information

• Product Name: (2R,4S,5R)-2-((E)-3-Benzyloxy-propenyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester
• CAS NO: 104863-83-4
• Molecular Weight: 443.543
• Mol File: 104863-83-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4S,5R)-2-((E)-3-Benzyloxy-propenyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4S,5R)-2-((E)-3-Benzyloxy-propenyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(104863-83-4)
• EPA Substance Registry System: (2R,4S,5R)-2-((E)-3-Benzyloxy-propenyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester(104863-83-4)

Safety Data

• Hazardous Substances Data: 104863-83-4(Hazardous Substances Data)

Upstream product

• 104863-81-2 E-4-benzyloxybut-2-enal dimethyl acetal 
• 104863-92-5 (1R,2S)-1-phenyl-2-benzyloxycarbonylamino-1-propanol 

Downstream Products

• 81801-09-4 4-O-benzyl-2,3-O-isopropylidene-D-threose 
• 104863-88-9 (2S,4S,5R)-2-((1R,2S)-3-Benzyloxy-1,2-dihydroxy-propyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 104863-88-9 (2S,4S,5R)-2-((1S,2R)-3-Benzyloxy-1,2-dihydroxy-propyl)-4-methyl-5-phenyl-oxazolidine-3-carboxylic acid benzyl ester 

Relevant articles and documents

ASYMMETRIC DIHYDROXYLATIONS VIA CHIRAL OXAZOLIDINES

The title compounds,new chirally masked α,β unsaturated aldehydes, undergo diastereoselective dihydroxilation reactions with 45-60percent diastereoisomeric excesses; chromatographic purification of the major diols, di-O-protection and auxiliary removal afford optically pure α β dialkoxy aldehydes.