104889-75-0Relevant academic research and scientific papers
ISOXAZOL-ROUTE ZU CYANO-SEMIBULLVALENEN
Askani, R.,Littmann, M.
, p. 5519 - 5520 (2007/10/02)
Based on the decarboxylative ring opening of 3-carboxyisoxazoles a new reaction sequence for the introduction of cyano groups on ketone 1 a is described.The isoxazoles 4 and 5 have been obtained by the cycloaddition of carboethoxyformonitrile oxide with enamines 2 a /3 a and removal of the morpholine ring by Cope elimination.The semibullvalenes 7 and 8 were prepared.
