104900-84-7

Basic information

• Product Name: Benzene, [2-[(1,1-dimethylethyl)sulfonyl]-1-methylethyl]-
• CAS NO: 104900-84-7
• Molecular Formula: C13H20O2S
• Molecular Weight: 240.367
• Mol File: 104900-84-7.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [2-[(1,1-dimethylethyl)sulfonyl]-1-methylethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-[(1,1-dimethylethyl)sulfonyl]-1-methylethyl]-(104900-84-7)
• EPA Substance Registry System: Benzene, [2-[(1,1-dimethylethyl)sulfonyl]-1-methylethyl]-(104900-84-7)

Safety Data

• Hazardous Substances Data: 104900-84-7(Hazardous Substances Data)

Upstream product

• 69113-46-8 (E)-tert-butyl 1-propenyl sulfone 

Relevant articles and documents

Organic synthesis with sulphones no. XXXIV. Uncatalysed addition versus nickel catalysed coupling reaction of vinylic sulfones with Grignard reagents. A stereoselective synthesis of olefins and dienes

Grignard reagents undergo Michael addition to vinylic sulfones.With a β-β-disubstituted vinylic sulfone an unexpected dimer is obtained.Under nickel catalysis methyl, aryl and alkenyl Grignard reagents displace the sulfonyl group of the readily available α,β-unsaturated sulfones.Methyl, resp. phenyl substituted olefins or conjugated dienes are formed.Under appropriate conditions the reaction proceeds with complete retention of configuration.

Organic synthesis with sulfones no. XXXV. Iron catalysed condensation and hydrogenolysis of vinylic sulfones with Grignard reagents. A stereoselective synthesis of di- and trisubstituted olefins

Vinylic sulfones are readily available in the E or Z configuration.Condensation with primary Grignard reagents occurs stereospecifically in the presence of iron catalysts, leading to trisubstituted olefins.With secondary Grignards stereospecific hydrogenolysis to 1,2-disubstituted olefins is observed.