104914-52-5Relevant academic research and scientific papers
The reactions of 2-methyl-1,2,3-triazinium iodides and related compounds
Itoh,Nagata,Okada,Ohsawa
, p. 2283 - 2286 (2007/10/02)
The 2-methyl-1,2,3-triazinium iodides 2 reacted with various nucleophiles to give the corresponding 2,5-dihydroadducts. When 2 was treated with potassium superoxide, it was dimerized to 5,5'-bi(2-methyl-2,5-dihydrotriazinyl). The 2,5-dihydro-1,2,3-triazin
Redox properties of superoxide with 1,2,3-triazine derivatives
Itoh,Nagata,Okada,Ohsawa
, p. 7193 - 7196 (2007/10/02)
2-Methyl-1,2,3-triazinium iodide 1 and its dihydro derivative 2 were both allowed to react with potassium superoxide to give the same products, triazine dimer 3 and 5-oxo-triazine 4. These reactions showed the unique dual reactivities of superoxide.
OXIDATION OF 2,5-DIHYDRO-1,2,3-TRIAZINES BY m-CHLOROPERBENZOIC ACID
Itoh, Takashi,Ohsawa, Akio,Kaihoh, Terumitsu,Igeta, Hiroshi
, p. 33 - 36 (2007/10/02)
2,5-Dihydro-1,2,3-triazines were oxidized by m-chloroperbenzoic acid to give only 1,2,3-triazine 2-oxides, while the oxidation of 1,2,3-triazines yielded the mixtures of 1- and 2-oxides.In case of adopting 2-methyl-2,5-dihydro-1,2,3-triazines as starting materials, 2-methyltriazoles and 2,5-dihydro-5-oxo-1,2,3-triazine were obtained.
