104917-39-7Relevant academic research and scientific papers
EXPERIMENTAL TEST OF ALTERNATIVE HYPOTHESIS FOR ISOTOPE-POSITION SCRAMBLING IN THE PHOTOCHEMICAL WOLFF REARRANGEMENT OF AZIBENZIL
Blaustein, Michael A.,Berson, Jerome A.
, p. 1081 - 1084 (1981)
Photolysis of azibenzil-(13)CO in methanol gives partially scrambled methyl diphenylacetate and unscrambled recovered azibenzil.
Catalytic Decarboxylative Cross-Ketonisation of Aryl- and Alkylcarboxylic Acids using Magnetite Nanoparticles
Goossen, Lukas J.,Mamone, Patrizia,Oppel, Christoph
supporting information; experimental part, p. 57 - 63 (2011/03/22)
In the presence of catalytic amounts of magnetite nanopowder, mixtures of aromatic and aliphatic carboxylic acids are converted selectively into the corresponding aryl alkyl ketones. As by-products, only carbon dioxide and water are released. This catalytic cross-ketonisation allows the regioselective acylation of aromatic systems and, thus, represents a sustainable alternative to Friedel-Crafts acylations.
