104925-72-6Relevant academic research and scientific papers
Iridium-Catalyzed Hydrosilylation of Sulfur-Containing Olefins
Srinivas, Venu,Nakajima, Yumiko,Sato, Kazuhiko,Shimada, Shigeru
, p. 12 - 15 (2018)
Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables the preparation of an industrially important silane coupling agent.
N,N-Dimethylformamide-protected Fe2O3 Combined with Pt Nanoparticles: Characterization and Catalysis in Alkene Hydrosilylation
Nagata, Tatsuki,Tanaka, Tatsuya,Lin, Xianjin,Kondo, Ryota,Suzuki, Takeyuki,Kanda, Yasuharu,Toyao, Takashi,Shimizu, Ken-ichi,Obora, Yasushi
, (2021/11/30)
We report a combination of N,N-dimethylformamide (DMF)-protected Fe2O3 nanoparticles (NPs) and Pt NPs for the hydrosilylation of various industrially relevant alkenes and tertiary silanes. The DMF-protected Fe2O3 and Pt NPs catalysts were characterized by transmission electron microscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. The catalyst of DMF-protected Fe2O3 NPs combined with Pt NPs can be recycled for five cycles by a simple extraction using hexane/DMF. The developed combination Fe2O3/Pt NPs catalyst is effective up to the 1-kilogram scale.
Iridium-Catalyzed Hydrosilylation of Unactivated Alkenes: Scope and Application to Late-Stage Functionalization
Xie, Xingze,Zhang, Xueyan,Yang, Haoyu,Ji, Xin,Li, Jianing,Ding, Shengtao
, p. 1085 - 1093 (2019/01/14)
Highly efficient and general Ir-catalyzed hydrosilylation of unactivated alkenes with excellent anti-Markovnikov regioselectivity was described. A broad scope of hydrosilylated products were synthesized economically and conveniently from commercially or n
