104936-71-2Relevant academic research and scientific papers
1,3-DIPOLAR CYCLOADDITIONS INDUCED BY CATION RADICALS. FORMATION OF 1,2,4-TRIAZOLES FROM OXIDATIVE ADDITION OF 1,4-DIPHENYLAZOMETHANE AND ARYL ALDEHYDE PHENYLHYDRAZONES TO NITRILES
Hoque, A. K. M. Mansurul,Kovelesky, Albert C.,Lee, Wang-Keun.,Shine, Henry J.
, p. 5655 - 5658 (1985)
Reaction of thianthrene cation radical perchlorate .(1+)*ClO4(1-)> with 1,4-diphenylazomethane (DPAM) in MeCN and EtCN led to the formation of 1,2,4-triazoles.Triazole formation is attributed to oxidative cycloaddition of benzaldehyde benzylhydrazone, the tautomer of DPAM, to the solvent nitriles.In confirmation, analogous cycloadditions were achieved by reaction of Th.(1+)*ClO4(1-) with some benzaldehyde phenylhydrazones in the same solvents.
