104976-06-9Relevant academic research and scientific papers
Cyclitol Reactions, XIV.- Synthesis of Building Units of Pseudo-α-D-glucopyranose and of Valiol
Paulsen, Hans,Deyn, Wolfgang von
, p. 133 - 140 (2007/10/02)
Regio- and stereoselective addition of ethyl 2-lithio-1,3-dithiolane-2-carboxylate to the enone 2, prepared from quebrachitol, yields the product 3 with an equatorial side-chain.Reduction of 3 leads to 7, which can be transformed into the hydroxymethyl de
