105017-74-1

Upstream product

• 10226-79-6 Pseudo-β-DL-gulopyranose-pentaacetat; DL-1-Acetoxymethyl-2,3,4,5-tetraacetoxy-cyclohexan 
• 10226-79-6 DL-(1/2,3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 64145-55-7 (+/-)-(1S,2S,4S)-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-ol 
• 10226-79-6 DL-(1,2/3,4,5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 139277-19-3 (1S,2S,3S,4R,5R)-3-Benzyloxy-5-benzyloxymethyl-2-phenylsulfanyl-7-oxa-bicyclo[2.2.1]heptane 
• 139277-14-8 (4aS,8R,8aS)-7-Benzenesulfonyl-8-benzyloxy-4a,5,8,8a-tetrahydro-4H-benzo[1,3]dioxine 
• 139277-13-7 (1S,2R,6S)-3-Benzenesulfonyl-2-benzyloxy-6-benzyloxymethyl-cyclohex-3-enol 
• 139277-11-5 (1R,2R,3R,4S,5S)-2-Benzenesulfonyl-3-benzyloxy-5-benzyloxymethyl-7-oxa-bicyclo[2.2.1]heptane 
• 10226-79-6 DL-(1,2,3/4,5)-5-acetoxymethyl-1,2,3,4-tetra-acetoxycyclohexane 
• 10226-79-6 DL-(1,2,4,5/3)-5-acetoxymethyl-1,2,3,4-tetra-acetoxycyclohexane 
• 10226-79-6 DL-penta-O-acetyl-(1,3,5/2,4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 64589-25-9 exo-2, endo-3-diacetoxy-endo-5-acetoxymethyl-7-oxabicyclo[2.2.1]heptane 
• 10226-79-6 DL-(1,2,3,4/5)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 64716-98-9 2,3:4,7-di-O-isopropylidene-(1,2,3,5/4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 

Downstream Products

• 97321-80-7 (1SR,2SR,3SR,5SR,8RS,10SR,12RS)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 97321-80-7 (1SR,2SR,3SR,5SR,8RS,10SR,12SR)-5,12-diphenyl-4,6,11,13-tetraoxatricyclo<8.3.0.0^3,8>tridecan-2-ol 
• 10226-73-0 DL-(1,5/2,3,4)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 10226-79-6 DL-(1,5/2,3,4)-5-acetoxymethyl-1,2,3,4-tetra-acetoxycyclohexane 
• 10226-79-6 DL-(1,2,3,5/4)-5-acethoxymethyl-1,2,3,4-tetra-O-acetyl-1,2,3,4-cyclohexanetetrol 
• 10226-73-0 (1R,2R,3S,4R,5R)-5-Hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 64714-19-8 Toluene-4-sulfonic acid (3aR,4R,5aS,9aS,9bR)-2,2,8,8-tetramethyl-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-yl ester 
• 117938-24-6 (2R,4aR,6R,7S,8S,8aR)-6,7,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 117902-50-8 (1RS,3RS,6RS,8RS,9SR,10SR)-8,9,10-trihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117938-24-6 (4aR,6S,7S,8S,8aR)-6,7,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 134428-47-0 6-O-acetyl-1,2,3-tri-O-benzyl-5a-carba-α-DL-glucopyranose 
• 125258-11-9 DL-(1,2,4/3,5)-1,2,3-tri-O-benzyl-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 134428-50-5 6-O-acetyl-1,2,3-tri-O-benzyl-4-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-5a-carba-α-L-glucopyranose 
• 134428-50-5 6-O-acetyl-1,2,3-tri-O-benzyl-4-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-5a-carba-α-D-glucopyranose 

Relevant academic research and scientific papers

A norbornyl route to cyclohexitols: Structural diversity in fragmentation through functional group switching. Synthesis of α- and β- galactose, α-talose and α-fucopyranose carbasugars

A novel fragmentation sequence has been executed within the norbornane system, involving C1-C7 bond scission, to extract a versatile, highly functionalized cyclohexanoid moiety. Its further evolution towards a range-of carbasugars is described. (C) 2000 Elsevier Science Ltd.

Strain-Directed Bridge Cleavage of (Phenylsulfonyl)-7-oxabicycloheptane Derivatives: Application to the Total Synthesis of Carba-α-DL-glucopyranose

New methodology to prepare highly oxygenated cyclohexenylsulfones by regioselective β-elimination of (phenylsulfonyl)-7-oxabicycloheptane derivatives has been developed, and its application to the total synthesis of carba-α-DL-glucopyranose is desc

Cyclitol Reactions, XIII.- Synthesis of Pseudosugars from D-Glucose by Intramolecular Horner-Emmons Olefination

The reaction of the aldehyde 3, prepared from D-glucose diethyl dithioacetal via 1 and 2, with lithium dimethyl methylphosphonat yields the adduct 4.Conversion of 4 into 9 followed by Swern oxidation results in the enone 6.Hydrogenation of 6 leads to pseu

SYNTHESIS OF FOUR NEW DIASTEREOISOMERS OF DL-5-HYDROXYMETHYL-1,2,3,4-CYCLOHEXANETETROL

Four new diastereoisomers of the pseudo-sugar DL-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol, having (1,2,3,4/5)- (2), (1,5/2,3,4)- (3), (1,2,3/4,5)- (4), and (1,2,4,5/3)-configurations (5), have been synthesised by unambiguous sequences from readily availa