1050264-83-9Relevant academic research and scientific papers
Chirality transfer from epoxide to carbanion: Base-induced alkylation of O-carbamoyl cyanohydrins of β-silyl-α,β-epoxy aldehyde
Sasaki, Michiko,Kawanishi, Eiji,Shirakawa, Yuri,Kawahata, Masatoshi,Masu, Hyuma,Yamaguchi, Kentaro,Takeda, Kei
supporting information; experimental part, p. 3061 - 3064 (2009/05/26)
Enantioselective C-C bond formation at an α-position of a nitrile group with an external electrophile can be realized, although in modest ee, with the aid of both the concerted process of an epoxysilane rearrangement and a carbamoyl group. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
