105037-85-2Relevant articles and documents
Total Synthesis of 1-Oxomiltirone and Arucadiol
Chai, Uiseong,Kang, Juyeon,Mac, Dinh Hung,Oh, Chang Ho,Seong, Chaehyeon
, p. 1953 - 1956 (2020)
A practical and efficient approach for the total synthesis of arucadiol and 1-oxomiltirone is reported. The key step which involves an intramolecular [4+2] cycloaddition catalyzed by gold(III) bromide or copper(II) triflate leads to the formation of 6-6-6-fused aromatic abietane core.
Use of conjugated dienones in cyclialkylations: Total syntheses of arucadiol, 1,2-didehydromiltirone, (±)-hinokione, (±)-nimbidiol, sageone, and miltirone
Majetich, George,Liu, Shuang,Fang, Jing,Siesel, David,Zhang, Yong
, p. 6928 - 6951 (2007/10/03)
Functionalized hydrophenanthrenes can be prepared using a cyclialkylation-based strategy. These annulations are highly dependent on the directing effects of the arene substitutents and on conformational considerations. The utility of this methodology was featured in the syntheses of six diterpenoids.