105040-72-0

Upstream product

• 2568-20-9 2-(3-oxopropyl)cyclohexanone 
• 132440-40-5 9-((E)-3,4-Bis-trimethylsilanyl-but-2-enyl)-9-bora-bicyclo[3.3.1]nonane 
• 105040-62-8 3,4-Bis-trimethylsilanyl-buta-1,2-diene 

Relevant academic research and scientific papers

Stereoselective Synthesis of Terminal 1,3-Butadienes by the Condensation Reaction of Aldehydes and Ketones with the γ-Trimethylsilyl-Substituted Allylboranes

Allylboranes 7-12, readily prepared from allenylsilanes 1-6 by hydroboration with 9-borabicyclononane, smoothly condense with aldehydes and ketones to afford, after basic or acidic workup to promote the Peterson olefination reaction, a variety of t

Stereoselective Synthesis of 2--1,3-butadienes

Allylborane 3, readily prepared from 1,2-bis-(trimethylsilyl)-2,3-butadiene by hydroboration with 9-borabicyclononane, smoothly condenses with aldehydes and ketones to afford, after basic or acidic workup, a variety of 2--1,3-butadienes with the dienes derived from aldehydes having high isomeric purity.