10506-34-0Relevant academic research and scientific papers
Oxidative desulfurization-fluorination reaction promoted by [bdmim][F] for the synthesis of difluorinated methyl ethers
Bouvet, Sébastien,Pégot, Bruce,Diter, Patrick,Marrot, Jér?me,Magnier, Emmanuel
, p. 1682 - 1686 (2015/03/14)
A new ionic liquid [bdmim][F] has been prepared and fully characterized. Its potential as a fluoride source for the desulfurization-fluorination process has been evaluated with success. The carbon-sulfur double bond of xanthates and thiocarbonates has bee
Constructing the OCF2O moiety using BrF3
Hagooly, Youlia,Rozen, Shlomo
, p. 6780 - 6783 (2008/12/22)
(Chemical Equation Presented) A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF 3. The fluorination step is complete in seconds with moderate to high yields under mild conditions.
Preparation of alkyl and aryl chlorodifluoromethyl ethers using BrF 3
Hagooly, Youlia,Sasson, Revital,Welch, Michael J.,Rozen, Shlomo
experimental part, p. 2875 - 2880 (2009/04/07)
Both alkyl and aryl chlorothioformates could readily be obtained from the corresponding alcohols and thiophosgene. These families of compounds were treated with BrF3 to form the corresponding alkyl and aryl chlorodifluoromethyl ethers in 60-85% yields. The method is suitable for constructing a variety of aliphatic as well as electron-deficient aromatic chlorodifluoromethyl ethers. The reactions proceed under mild conditions and short reaction times. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
