105065-75-6Relevant academic research and scientific papers
Sterically Hindered Free Radicals, XVII. The Addition of Diphenylmethyl Radicals to Radicophilic Olefins, and the Diastereomer Transformation of 2,3-Diaryl-2,3-bis(trimethylsilyloxy)succinonitriles
Neumann, Wilhelm P.,Stapel, Ralf
, p. 3432 - 3441 (2007/10/02)
The radicals Ph2C*-MMe3 2, M = C, Si, Ge, Sn, give with 2-tBuS-acrylonitrile (1) via a 1,4-C,N-addition not known until now exclusively the ketenimine 5, which dissociates reversibly even at 25 deg C.The less hindered 2-Me3SiO-acrylonitrile (6), on the ot
