1050675-91-6Relevant articles and documents
Practical method for asymmetric addition of arylboronic acids to α,β-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin, Kirill,Zhang, Qunying,Leanna, M. Robert
, p. 929 - 931 (2009)
A new practical method for the asymmetric Michael addition of arylboronic acids to α,β-unsaturated carbonyl compounds utilizing in situ generated chiral rhodium-binap-based catalyst has been developed to address the unavailability of the preformed catalys
A novel, C2-symmetric, chiral bis-cyclosulfinamide-olefin tridentate ligand in Rh-catalyzed asymmetric 1,4-additions
Zhang, Li,Tan, Mingchao,Zhou, Lihong,Zeng, Qingle
, p. 2778 - 2783 (2018)
A C2-symmetric, chiral bis-cyclosulfinamide-olefin ligand composed of two 1-oxo-2,3-dihydro-1,2-benzisothiazole moieties with rigid skeletons and a conformationally flexible butenylene chain is disclosed for the first time. HRMS and 1/sup
Dicyclic sulfamide-alkene chiral ligand as well as preparation method and application
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Paragraph 0025-0030; 0043-0044, (2021/05/13)
The invention discloses a dicyclic sulfamide-alkene chiral ligand as well as a preparation method and application. The structural characteristic of the dicyclic sulfamide-alkene chiral ligand is thatthe chiral ligand is a C2 symmetric compound formed by c
Room-temperature rhodium-catalyzed asymmetric 1,4-addition of potassium trifluoro(organo)borates
Gendrineau, Thomas,Genet, Jean-Pierre,Darses, Sylvain
supporting information; experimental part, p. 3486 - 3489 (2009/12/24)
For the first time the room-temperature rhodium-catalyzed asymmetric 1,4-addition of potassium aryltrifluoroborates to αβ-unsaturated substrates is described. Thanks to the use of a chiral diene as ligand for rhodium and triethylamine as base, to facilita