105102-68-9Relevant academic research and scientific papers
Mono(aryl)cobalt(II) compounds stabilized by bis ortho chelation
Van Der Zeijden, Adolphus A. H.,Van Koten, Gerard
, p. 4723 - 4725 (2008/10/08)
The reaction of Li2[C6H3(CH2NMe2) 2-o,o′]2 with CoIIX2L2 (L = py, PPh3, X = Cl, Br, I; L = PEt3, X = Cl) yields the air-sensitive compounds CoII[C6H3(CH2NMe2) 2-o,o′]X(L). From elemental analyses and UV and ESR spectral data it was concluded that the complexes are five-coordinate and have a square-pyramidal structure with an apical ligand L.
