1051371-07-3

Upstream product

• 15874-80-3 3-methyl-1-(phenylsulfonyl)but-2-ene 
• 106-96-7 propargyl bromide 
• 870-63-3 prenyl bromide 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 1051371-13-1 (2-isopropylcyclopenta-1,3-dienylsulfonyl)benzene 
• 1051371-09-5 (6-methyl-1-phenylhept-5-en-1-yn-4-ylsulfonyl)benzene 
• 1174411-61-0 1-chloro-4-(6-methyl-4-(phenylsulfonyl)hept-5-en-1-ynyl)benzene 
• 1174411-62-1 1-(4-(6-methyl-4-(phenylsulfonyl)hept-5-en-1-ynyl)phenyl)ethanone 
• 1174411-59-6 1-methyl-4-(6-methyl-4-(phenylsulfonyl)hept-5-en-1-ynyl)benzene 
• 1174411-60-9 1-methoxy-4-(6-methyl-4-(phenylsulfonyl)hept-5-en-1-ynyl)benzene 

Relevant academic research and scientific papers

Nature of the intermediates in gold(I)-catalyzed cyclizations of 1,5-enynes

The carbene or carbocationic nature of the intermediates in the gold-catalyzed cycloisomerization of 1,5-enynes can be revealed, depending on the ligands on the gold catalysts. Gold complexes with highly electron-donating ligands promote reactions that proceed via intermediates with carbene-like character, leading to products with a bicyclo[3.1.0]hexene skeleton. The intermediate cyclopropyl endo-gold carbenes formed in this cyclization have been trapped, for the first time, to give biscyclopropane derivatives in a reaction that proceeds in a concerted fashion, according to DFT calculations.

Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes

(Chemical Equation Presented) Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cycli