105180-15-2

Upstream product

• 13991-08-7 o-phenylenebis(diphenylphosphine) 
• 58466-03-8 (1,2-bis(diphenylphosphanyl)benzene)dichloridoplatinum(II) 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 58466-03-8 (1,2-bis(diphenylphosphanyl)benzene)dichloridoplatinum(II) 

Relevant academic research and scientific papers

UEBER DEN MECHANISMUS DER LICHT-INDUZIERTEN ELIMINIERUNG DES BIPHENYL-SYSTEMS AUS cis-BIS(PHENYL)PLATIN(II)-VERBINDUNGEN

We report the light-induced reductive elimination of the biphenyl system from compounds of the types bis(phenyl)2-1,2-bis(diphenylphosphano)ethan>platinum(II), bis(phenyl)2-cis-1,2-bis(diphenylphosphano)ethene>platinum(II) and bis(phenyl)2-1,2-bis(diphenylphosphano)benzene>platinum(II) with substituents in the platinum-bound phenyl rings.The elimination proceeds via a concerted reaction mechanism without any observable free radical involvement.