105197-44-2Relevant academic research and scientific papers
Copper-Catalyzed Coupling of Acyl Chlorides with gem-Difluorinated Organozinc Reagents via Acyl Dithiocarbamates
Ashirbaev, Salavat S.,Levin, Vitalij V.,Struchkova, Marina I.,Dilman, Alexander D.
, p. 478 - 483 (2017/12/15)
A cross-coupling of acyl chlorides with gem-difluorinated organozinc reagents affording difluorinated ketones is described. In the reaction, acyl chlorides are first treated with potassium dithiocarbamate to generate S-acyl dithiocarbamates, which couple with organozincs in the presence of a copper(I) catalyst.
Thermal Sigmatropic Rearrangement of Cinnamoyl Dithiocarbamic Anhydrides
Shah, K. K.,Shah, A.
, p. 1077 - 1078 (2007/10/02)
Cinnamoyl dithiocarbamic anhydrides (III) undergo rearrangement in refluxing acetone to give corresponding β-(dithiocarbamyl)phenylpropionic acids (V) via sigmatropic rearrangement of III, along with the cinnamic acid amides, via CS2 elimination.The
