105205-38-7Relevant academic research and scientific papers
Crystal and molecular structure of bis(η6-benzene)ruthenium(II) p-toluenesulfonate
Beck, Urs,Hummel, Wolfgang,Bürgi, Hans-Beat,Ludi, Andreas
, p. 20 - 22 (2008/10/08)
[Ru(C6H6)2] (tos)2 (tos = p-toluenesulfonate) crystallizes in the triclinic space group P1 with a = 7.065 (2) ?, b = 8.280 (2) ?, c = 11.060 (3) ?, α = 84.44 (2)°, β = 76.35 (2)°, γ = 68.42 (2)° (T = 125 K), and Z = 1. The structure was refined to 2.5% for 4438 reflections with Fo > 10σ(Fo). The two benzene rings of the sandwich cation are ecliptic, symmetry-related by a center of inversion at the Ru site. After correction for thermal motion average distances are Ru-C = 2.225 (1), C-C = 1.418 (1), and C-H (uncorrected) = 0.919 (14) ?. The Ru-center of the benzene plane distance is 1.717 ?.
