10522-32-4

Basic information

• Product Name: (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate
• Synonyms: (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate;Benzeneacetic acid (Z)-3,7-dimethyl-2,6-octadienyl ester;Einecs 234-069-5;neryl phenyl acetate
• CAS NO: 10522-32-4
• Molecular Formula: C18H24O2
• Molecular Weight: 272.38196
• EINECS: 234-069-5
• Mol File: 10522-32-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 378.1°Cat760mmHg
• Flash Point: 126.6°C
• Appearance: /
• Density: 0.981g/cm³
• Vapor Pressure: 6.45E-06mmHg at 25°C
• Refractive Index: 1.514
• CAS DataBase Reference: (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate(10522-32-4)
• EPA Substance Registry System: (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate(10522-32-4)

Safety Data

• Hazardous Substances Data: 10522-32-4(Hazardous Substances Data)

Usage

General Description

(Z)-3,7-dimethylocta-2,6-dienyl phenylacetate is a chemical compound with a complex structure consisting of a phenyl ring attached to a long chain with a double bond at the 3rd and 7th carbon atoms from the methyl end. (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate is commonly used in the production of perfumes and fragrances due to its pleasant aroma. It is also used as a flavoring agent in the food industry. Additionally, (Z)-3,7-dimethylocta-2,6-dienyl phenylacetate possesses insecticidal properties and is used in the formulation of insect repellents and pesticides. Furthermore, it has been studied for its potential applications in pharmaceuticals and cosmetics due to its unique chemical properties and potential biological activities.

InChI:InChI=1/C18H24O2/c1-15(2)8-7-9-16(3)12-13-20-18(19)14-17-10-5-4-6-11-17/h4-6,8,10-12H,7,9,13-14H2,1-3H3/b16-12-

Upstream product

• 103-82-2 phenylacetic acid 
• 106-24-1 Geraniol 
• 75178-11-9 Phenyl-acetic acid [2,2']bipyridinyl-6-yl ester 

Relevant articles and documents

Gd(OTf)3-catalyzed synthesis of geranyl esters for the intramolecular radical cyclization of their epoxides mediated by titanocene(III)

A selective and mild method for the esterification of a variety of carboxylic acids with geraniol is developed. We demonstrated that the use of triphenylphosphine, I2, 2-methylimidazole or imidazole and a catalytic amount of Gd(OTf)3 resulted to be more active than the previous protocols, providing a 16-membered library of geranyl esters in higher yields and in shorter reaction times. The use of essential oil of palmarosa (Cymbopogon martinii), enriched with geraniol, as a raw material for the synthesis of the target compounds complemented and proved how sustainable and eco-friendly this protocol is. Finally, the selective 6,7-epoxidation of the obtained geranyl esters led us to study their regio-controlled radical cyclization mediated by titanocene(iii) for the synthesis of novel (8-hydroxy-9,9-dimethyl-5-methylene cyclohexyl)methyl esters in moderate yields and with excellent stereoselectivities.

A USEFUL METHOD FOR SELECTIVE ACYLATION OF ALCOHOLS USING 2,2'-BIPYRIDYL-6-YL CARBOXYLATE AND CESIUM FLUORIDE

Primary and secondary alcohols are acylated under mild conditions by the of use 2,2'-bipyridyl-6-yl carboxylates and cesium fluoride.Furthermore, the reaction is successfully applied to selective acylation of a primary carbinol group of diols containing primary and secondary carbinol groups or exclusive O-acylation of aromatic amino alcohols.