105247-50-5Relevant academic research and scientific papers
Formation of 1,3-Dithiolanes and 1,3-Dithianes on Electroreduction of ω-Chloroalkyl Dithiocarboxylates
Gade, Thomas,Streek, Michael,Voss, Juergen
, p. 2245 - 2250 (2007/10/02)
Cyclic thioacetals of type 4 and 5 are formed by intramolecular nucleophilic attack in the cathodic reduction of the ω-chloroalkyl dithiocarboxylates 1 and 2.The yield of 2-tert-butyl-1,3-dithiane (4b) is 52percent, whereas elimination of dithiocarboxylate anions occurs to a considerable extent in the other cases.
Synthese de dithioesters par reaction des dithioacides ou de leurs sels (magnesiens mixtes ou d'ammonium quaternaire) sur les derives halogenes, les aldehydes et les epoxydes
Bonnans-Plaisance, Chantal,Gressier, Jean-Claude,Levesque, Guy,Mahjoub, Ahmed
, p. 891 - 899 (2007/10/02)
In a previous paper we have shown that quaternary ammonium salts of dithiocarboxylic acids could substitute labile chlorine atoms of PVC without elimination of hydrochloric acid.This results demonstrated the high nucleophilic power associated with a low b
