105247-50-5Relevant articles and documents
Formation of 1,3-Dithiolanes and 1,3-Dithianes on Electroreduction of ω-Chloroalkyl Dithiocarboxylates
Gade, Thomas,Streek, Michael,Voss, Juergen
, p. 2245 - 2250 (2007/10/02)
Cyclic thioacetals of type 4 and 5 are formed by intramolecular nucleophilic attack in the cathodic reduction of the ω-chloroalkyl dithiocarboxylates 1 and 2.The yield of 2-tert-butyl-1,3-dithiane (4b) is 52percent, whereas elimination of dithiocarboxylate anions occurs to a considerable extent in the other cases.