105314-80-5Relevant academic research and scientific papers
Synthesis, structural and spectroscopic study of aromatic thioester compounds
Jios, Jorge L.,Kirin, Srecko I.,Weyhermüller, Thomas,Metzler-Nolte, Nils,Della Védova, Carlos O.
, p. 53 - 59 (2006)
Eight novel thioesters were obtained and characterized by elemental analysis, mass spectrometry, infrared and NMR spectroscopy. The data were analyzed on the basis of the relevant resonance structures. The X-ray single crystal structure of o-methoxythiophenyl 4-methylbenzoate is reported.
Cobalt carbonyl catalyzed reaction of mercaptans with Schiff bases and carbon monoxide
Antebi, Shlomo,Alper, Howard
, p. 2010 - 2012 (2007/10/02)
Thiophenols and p-methylbenzyl mercaptan react with Schiff bases and carbon monoxide in benzene, in the presence of cobalt carbonyl, to give amides as the pricipal products.These amides arise from cleavage of the carbon-nitrogen double bond of the reactant imine.The reaction is applicable to a variety of Schiff bases (i.e. aliphatic, benzylic, aromatic).Thioesters and olefins are usually obtained as reaction by-products.
