105336-41-2

Basic information

• Product Name: Benzenamine, N,N-dibutyl-3,4-dimethyl-
• CAS NO: 105336-41-2
• Molecular Formula: C16H27N
• Molecular Weight: 233.397
• Mol File: 105336-41-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N-dibutyl-3,4-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N-dibutyl-3,4-dimethyl-(105336-41-2)
• EPA Substance Registry System: Benzenamine, N,N-dibutyl-3,4-dimethyl-(105336-41-2)

Safety Data

• Hazardous Substances Data: 105336-41-2(Hazardous Substances Data)

Upstream product

• 583-71-1 4-bromo-o-xylene 
• 111-92-2 dibutylamine 

Relevant articles and documents

Design of a versatile and improved precatalyst scaffold for palladium-catalyzed cross-coupling: (η3-1-tBu-indenyl)2(μ-Cl)2Pd2

We describe the development of (η3-1-tBu-indenyl)2(μ-Cl)2Pd2, a versatile precatalyst scaffold for Pd-catalyzed cross-coupling. Our new system is more active than commercially available (η3-cinnamyl)2(μ-Cl)2Pd2 and is compatible with a range of NHC and phosphine ligands. Precatalysts of the type (η3-1-tBu-indenyl)Pd(Cl)(L) can either be isolated through the reaction of (η3-1-tBu-indenyl)2(μ-Cl)2Pd2 with the appropriate ligand or generated in situ, which offers advantages for ligand screening. We show that the (η3-1-tBu-indenyl)2(μ-Cl)2Pd2 scaffold generates highly active systems for a number of challenging cross-coupling reactions. The reason for the improved catalytic activity of systems generated from the (η3-1-tBu-indenyl)2(μ-Cl)2Pd2 scaffold compared to (η3-cinnamyl)2(μ-Cl)2Pd2 is that inactive PdI dimers are not formed during catalysis.