10536-63-7Relevant academic research and scientific papers
Octamethyltetrasilaparacyclophane. Cyclophanes Bridged by Polysilanes
Sakurai, Hideki,Hoshi, Satoshi,Kamiya, Akihiko,Hosomi, Akira,Kabuto, Chizuko
, p. 1781 - 1784 (1986)
1,1,2,2,9,9,10,10-Octamethyl-1,2,9,210-tetrasilaparacyclophane, the first paracyclophane bridged by heteroatoms, has been prepared.Uv, IR, and 1H- 13C- and 29Si-NMR spectral together with X-ray crystallographic data are recorded.The compound dis
2D Oligosilyl Metal–Organic Frameworks as Multi-state Switchable Materials
Burns, David A.,Press, Eric M.,Siegler,Klausen, Rebekka S.,Thoi, V. Sara
, p. 763 - 768 (2020)
We report the synthesis of a set of 2D metal–organic frameworks (MOFs) constructed with organosilicon-based linkers. These oligosilyl MOFs feature linear SinMe2n(C6H4CO2H)2 ligands (lin-Si
Thermosalience in Macrocycle-Based Soft Crystals via Anisotropic Deformation of Disilanyl Architecture
Omoto, Kenichiro,Nakae, Toyotaka,Nishio, Masaki,Yamanoi, Yoshinori,Kasai, Hidetaka,Nishibori, Eiji,Mashimo, Takaki,Seki, Tomohiro,Ito, Hajime,Nakamura, Kazuki,Kobayashi, Norihisa,Nakayama, Naofumi,Goto, Hitoshi,Nishihara, Hiroshi
, p. 12651 - 12657 (2020)
We describe here the preparation of soft crystals using disilanyl macrocycle C4 possessing four p-phenylenes circularly connected by four flexible disilane bonds. Single crystals of C4 exhibited a reversible thermal single-crystal-to-single-crystal (SCSC)
Photoinduced Charge Separation in Molecular Silicon
Zhou, Jiawang,Surampudi, Sravan K.,Bragg, Arthur E.,Klausen, Rebekka S.
, p. 6204 - 6207 (2016)
Interest in molecular silicon semiconductors arises from the properties shared with bulk silicon like earth abundance and the unique architectures accessible from a structure distinctly different than rigid π-conjugated organic semiconductors. We report u
Silicon-carbon unsaturated compounds XLIV. Photochemical behavior of permethylated p-(disilanylene)phenylene oligomers
Ishikawa, Mitsuo,Watanabe, Koki,Sakamoto, Hiromu,Kunai, Atsutaka
, p. 61 - 68 (2007/10/02)
The p-(disilanylene)phenylene oligomers, Me3Si(Me2Si-C6H4-SiMe2)nSiMe3 with n = 2-4 (2, 3, and 4) were prepared and their photochemical behavior was investigated in a benzene solution.Photolysis of 2 in the presence of isobutene afforded 1-isobutyldimethy
Magnetic interaction between two triplet nitrene units through diphenylsilane and 1,2-diphenyldisilane couplers
Doi, Takatsugu,Ichimura, Andrew S.,Koga, Noboru,Iwamura, Hiizu
, p. 8928 - 8932 (2007/10/02)
m,m′-,m,p′-, and p,p′-Bis(azidophenyl)dimethylsilanes 1a and 1,2-bis(azidophenyl)-1,1,2,2-tetramethyldisilanes 2a were prepared, and the dipolar and exchange couplings in the corresponding dinitrenes 1n and 2n generated photochemically were investigated b
