1053628-75-3

Upstream product

• 171815-15-9 <1S-(1α,2α,3β,4β,5α,6β)>-3-Azido-5,6-bis(methoxymethoxy)cyclohexane-1,2,4-triol 
• 171815-13-7 <1R-(1α,2β,3α,4β,5α,6α)>-5-(Benzyloxy)-3,4-bis(methoxymethoxy)-7-oxabicyclo<4.1.0>heptan-2-ol 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 171815-14-8 <1R-(1α,2β,3α,4β,5α,6α)>-3,4-Bis(methoxymethoxy)-7-oxabicyclo<4.1.0>heptane-2,5-diol 
• 136471-95-9 methyl 3,4-bis(O-methoxymethyl)-2,6-bis-α-D-glucopyranoside 
• 136471-96-0 Methyl 6-deoxy-3,4-bis-O-(methoxymethyl)-2-O-(p-toluenesulfonyl)-α-D-xylo-5-hexenopyranoside 
• 136471-97-1 methyl 2-O-benzyl-6-deoxy-3,4-bis(O-methoxymethyl)-α-D-xylo-hex-5-enopyranoside 
• 136471-99-3 <2S-(2α,3β,4α)>-4-(Benzyloxy)-2,3-bis(methoxymethoxy)-5-cyclohexen-1-one 
• 171815-12-6 <1S-(1α,2β,3α,4β)>-4-(Benzyloxy)-2,3-bis(methoxymethoxy)-5-cyclohexen-1-ol 
• 160835-77-8 methyl 6-deoxy-3,4-bis(O-methoxymethyl)-α-D-xylo-hex-5-enopyranoside 
• 54497-89-1 methyl 2,6-bis-α-D-glucopyranoside 

Downstream Products

• 171815-17-1 N-<<1S-(1α,2β,3α,4β,5β,6α)>-1,2,3,4,5-Pentahydroxycyclohex-6-yl>-N'-(2,3,4,6-tetra-O-α-D-glucopyranosyl)thiourea 
• 171815-18-2 2,3,4,6-Tetra-O-benzyl-1-deoxy-1-<<<3aS-(3aα,4α,5α,6β,7α,7aα)>-4,5,6,7-tetrahydroxy-3a,4,5,6,7,7a-hexahydrobenzoxazol-2-yl>amino>-α-D-glucopyranose 

Relevant academic research and scientific papers

Synthesis of a 2-aminohexahydrobenzoxazole analogue related to trehazolin

2-Aminohexahydrobenzoxazole analogue 1a, related to trehazolin (2) was synthesized using the Ferrier reaction as a key step. The structural elucidation of this compound by NMR analysis indicated that it is an inseparable mixture of three components (1a-c) which in turn stems from the propensity of la to partially undergo both transcyclization (1a → 1b) of the aminooxazoline between the hydroxy group at the C-1 position of aminocyclitol in the aglycon moiety and the hydroxy group at the C-2 position of D-glucose moiety and successive transformation (1b → 1c) of the D-glucose moiety from a pyranose to a furanose structure.