105363-57-3

Basic information

• Product Name: 3-Pentanol, 1-[(4-methylphenyl)sulfonyl]-
• CAS NO: 105363-57-3
• Molecular Formula: C12H18O3S
• Molecular Weight: 242.339
• Mol File: 105363-57-3.mol

Chemical Properties

• CAS DataBase Reference: 3-Pentanol, 1-[(4-methylphenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanol, 1-[(4-methylphenyl)sulfonyl]-(105363-57-3)
• EPA Substance Registry System: 3-Pentanol, 1-[(4-methylphenyl)sulfonyl]-(105363-57-3)

Safety Data

• Hazardous Substances Data: 105363-57-3(Hazardous Substances Data)

Upstream product

• 536-57-2 p-toluene sulfinic acid 
• 1629-58-9 4-penten-3-one 
• 106-88-7 ethyloxirane 
• 3185-99-7 Methyl p-tolyl sulfone 

Downstream Products

• 131701-88-7 (S)-1-(Toluene-4-sulfonyl)-pentan-3-ol 
• 132059-17-7 (R)-(-)-5-p-toluenesulfonyl-3-pentanol 
• 139951-18-1 1-Methyl-4-(3-methylsulfanyl-pentane-1-sulfonyl)-benzene 
• 121034-10-4 1-((E)-3-Methoxy-pent-2-ene-1-sulfonyl)-4-methyl-benzene 
• 121034-09-1 1-((Z)-3-Methoxy-pent-2-ene-1-sulfonyl)-4-methyl-benzene 
• 121033-99-6 (E)-3-methoxy-1-tosyl-1-pentene 
• 145049-10-1 Carbonic acid ethyl ester (R)-1-ethyl-3-(toluene-4-sulfonyl)-propyl ester 
• 145049-11-2 (R)-5-Ethyl-3-(toluene-4-sulfonyl)-dihydro-furan-2-one 
• 121033-97-4 1-(3-Methoxy-pentane-1-sulfonyl)-4-methyl-benzene 
• 139951-16-9 Methanesulfonic acid 1-ethyl-3-(toluene-4-sulfonyl)-propyl ester 
• 145049-07-6 Acetic acid (R)-1-ethyl-3-(toluene-4-sulfonyl)-propyl ester 

Relevant articles and documents

"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones

It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was

Stereochemistry of the Conversion of γ-substituted (E)-Vinylsulfones to the Corresponding Allylsulfones. Determination of the Relative Degree of "Syn-Effect"

The relative degree of "syn-effect" for the γ-substituted vinylsulfones in their conversion to the corresponding allylsulfones with 1,8-diazabicycloundec-7-ene (DBU) was determined by observing E/Z ratios of the resulting allylsulfones as follows:

EPOXIDE RING OPENING BY α-SULFONYL CARBANIONS. SYNTHESIS OF γ-HYDROXY SULFONES AND TRIFLONES

γ-Hydroxy sulfones and triflones are obtained in moderate to excellent yields when n-butyl lithium is added to a mixture of sulfone and epoxide in toluene at 65 deg C followed by heating from four to twenty hours at 110 deg C.